能源是人类生存和发展的重要支柱,研究化学反应过程中的能量变化在能源紧缺的今天具有重要的理论意义,已知下列热化学方程式
① |
H2(g)+ O2(g)= H2O(g) △H =﹣242kJ /mol; |
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② |
2H2(g)+ O2(g)= 2H2O(l) △H =﹣572kJ/mol; |
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③ |
C(s)+ O2(g)= CO(g) △H =﹣110.5kJ/moL; |
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④ |
C(s)+ O2(g)= CO2(g) △H =﹣393.5kJ/moL; |
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⑤ |
CO2(g)+ 2H2O(g)= CH4(g)+ 2O2(g)△H =" +" 802kJ/moL |
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化学键 |
O=O |
C-C |
H-H |
O-O |
C-O |
O-H |
C-H |
|
键能kJ/mol |
497 |
348 |
436 |
142 |
351 |
463 |
414 |
|
则下列说法正确的是
A.H2燃烧热的热化学方程式为H2(g)+ O2(g)= H2O(g) △H =﹣242kJ /mol
B.热化学方程式:C(s)+ H2O(g) H2(g)+ CO(g) △H =" +" 175.5 kJ/moL
C.CH4的燃烧热△H ="—" 802 kJ/moL
D.估算出C=O键能为800kJ/moL