为确定某溶液的离子组成，进行实验：
①测定溶液的pH值，溶液显碱性
②取少量溶液加稀盐酸至溶液呈酸性，产生能使澄清石灰水变浑浊的气体
③在上述溶液中再滴加Ba(NO3)2溶液，产生白色沉淀
④取上层清液继续滴加Ba(NO3)2溶液至无沉淀时，再滴加Ag NO3溶液，产生白色沉淀。根据以上实验,以下对原溶液的推测正确的是
| A．一定有CO32－离子存在 | B．不能确定是否存在HCO3－离子存在 |
| C．一定有C1–离子存在 | D．一定有SO32－离子存在 |
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