已知下列热化学方程式:
①CH3COOH(1)+202(g)=2CO2(g)+2H2O(1) △H1=" —870.3" kJ·mol—1
②C(s)+O2(g)=CO2(g) △H2=" —393.5" kJ·mol—1
③H2(g)+1/2O2(g)=H2O(1) △H3=" —285.8" kJ·mol—1
则反应④2C(s)+2H2(g)+O2(g)=CH3COOH(1)的焓变为( )
A.+488.3 kJ·mol—1 |
B.—224.15 kJ·mol—1 |
C.—488.3 kJ·mol—1 |
D.+244.15 kJ·mol—1 |